Preheat the oven to 350 degrees F and line a 9x9 inch metal baking pan with parchment paper for easy removal. Set to the side. Add the butter and chocolate chips to a large microwave-safe bowl. Melt butter and chocolate in 30-second increments, mixing until smooth.
113 grams unsalted butter, 270 grams chocolate chips
Sift the cocoa powder, salt, and espresso powder together and add to the melted chocolate. Stir until smooth.
50 grams unsweetened cocoa powder, 6 grams salt, 2 grams espresso powder, optional
Next, add the white sugar and brown sugar and stir until combined.
175 grams white sugar, 175 grams light brown sugar
Whisk in the eggs one at a time and mix until smooth, then stir in the sourdough discard and vanilla extract until the white streaks are gone.
2 large eggs, 4 grams vanilla extract, 120 grams sourdough discard, room temperature
Lastly, fold in the flour until just incorporated.
140 grams all-purpose flour, sifted
Pour the batter into the prepared pan and smooth the chocolate mixture with a rubber spatula.
Bake for 35-40 minutes.These brownies are super fudgy and gooey, so the toothpick test isn't the most reliable way to check if the brownies are finished baking. Instead, I look to see if the sides of the brownies are pulling away from the edges of the parchment paper and the center looks a little soft. Careful not to overbake. The brownies will continue to cook even out of the oven, so it's better to undercook than overcook them. Remove the warm brownies from the oven, place them on a wire rack, and cool them completely before topping them with the chocolate ganache.